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http://hdl.handle.net/10261/190630
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dc.contributor.author | Domínguez, Zoe | - |
dc.contributor.author | López-Rodríguez, Rocío | - |
dc.contributor.author | Álvarez, Eleuterio | - |
dc.contributor.author | Abbate, Sergio | - |
dc.contributor.author | Longhi, Giovanna | - |
dc.contributor.author | Pischel, Uwe | - |
dc.contributor.author | Ros, Abel | - |
dc.date.accessioned | 2019-09-13T06:52:54Z | - |
dc.date.available | 2019-09-13T06:52:54Z | - |
dc.date.issued | 2018-08-27 | - |
dc.identifier.citation | Chemistry - a European Journal 24(48): 12660-12668 (2018) | - |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.uri | http://hdl.handle.net/10261/190630 | - |
dc.description.abstract | Three helicenes based on a borylated arylisoquinoline skeleton have been prepared in their enantiopure forms and characterized with respect to their photophysical properties, including the use of chiroptical spectroscopies. The dyes show varying charge-transfer characteristics and efficient emission (quantum yields between 0.13 and 0.30, in toluene), which is governed by the electron-donor substitution (p-MeO-phenyl, p-MeN-phenyl) at the helicene. Marked differences in the emission wavelength and Stokes shift are observed, with the dimethylamino-substituted derivative emitting most red-shifted (maximum at ca. 590 nm) and displaying the highest Stokes shift (ca. 6000 cm) in toluene. The helicenes show electronic circular dichroism (ECD) and significant circularly polarized luminescence (CPL) with dissymmetry factors of up to 3.5×10. The sign of the ECD band corresponding to the first transition and of the CPL spectrum depend sensibly on the electron-donor substitution. | - |
dc.description.sponsorship | This work was financially supported by the Spanish Ministry of Economy, Industry, and Competitiveness (CTQ2014‐54729‐C2‐1‐P and CTQ2017‐89832‐P for U.P., CTQ2013‐48164‐C2‐1‐P and CTQ2013‐48164‐C2‐2‐P for A.R., Ramon y Cajal contract RYC‐2013‐12585 for A.R., Ph.D. fellowship BES‐2015‐074458 for Z.D.), the ERDF, the Junta de Andalucía (2012/FQM‐2140 for U.P. and 2012/FQM‐1078 for A.R.), Fondazione Cariplo and Regione Lombardia (Big&Open Data Innovation Laboratory, BODaI‐Lab, University of Brescia). | - |
dc.publisher | John Wiley & Sons | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014‐54729‐C2‐1‐P | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/RYC‐2013‐12585 | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013‐48164‐C2‐2‐P | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013‐48164‐C2‐1‐P | - |
dc.rights | closedAccess | - |
dc.subject | Push-pull chromophores | - |
dc.subject | Circularly polarized luminescence | - |
dc.subject | Circular dichroism | - |
dc.subject | Helicene | - |
dc.subject | Boron | - |
dc.title | Azabora[5]helicene charge-transfer dyes show efficient and spectrally variable circularly polarized luminescence | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/chem.201801908 | - |
dc.relation.publisherversion | https://doi.org/10.1002/chem.201801908 | - |
dc.identifier.e-issn | 1521-3765 | - |
dc.date.updated | 2019-09-13T06:52:54Z | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Ministerio de Ciencia, Innovación y Universidades (España) | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Junta de Andalucía | - |
dc.contributor.funder | Fondazione Banca del Monte di Lombardia | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100011011 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
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