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Azabora[5]helicene charge-transfer dyes show efficient and spectrally variable circularly polarized luminescence

AuthorsDomínguez, Zoe; López-Rodríguez, Rocío ; Álvarez, Eleuterio ; Abbate, Sergio; Longhi, Giovanna; Pischel, Uwe; Ros, Abel
KeywordsPush-pull chromophores
Circularly polarized luminescence
Circular dichroism
Issue Date27-Aug-2018
PublisherJohn Wiley & Sons
CitationChemistry - a European Journal 24(48): 12660-12668 (2018)
AbstractThree helicenes based on a borylated arylisoquinoline skeleton have been prepared in their enantiopure forms and characterized with respect to their photophysical properties, including the use of chiroptical spectroscopies. The dyes show varying charge-transfer characteristics and efficient emission (quantum yields between 0.13 and 0.30, in toluene), which is governed by the electron-donor substitution (p-MeO-phenyl, p-MeN-phenyl) at the helicene. Marked differences in the emission wavelength and Stokes shift are observed, with the dimethylamino-substituted derivative emitting most red-shifted (maximum at ca. 590 nm) and displaying the highest Stokes shift (ca. 6000 cm) in toluene. The helicenes show electronic circular dichroism (ECD) and significant circularly polarized luminescence (CPL) with dissymmetry factors of up to 3.5×10. The sign of the ECD band corresponding to the first transition and of the CPL spectrum depend sensibly on the electron-donor substitution.
Publisher version (URL)https://doi.org/10.1002/chem.201801908
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