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Cyanide-bridged tetradecanuclear RuII3MII11 clusters (MII = ZnII and CuII) based on the high connectivity building block [Ru3(HAT)(CN)12]6-: structural and photophysical properties

AuthorsHerrera, Juan Manuel; Colacio, Enrique; Mathonière, Corine; Choquesillo-Lazarte, Duane ; Ward, Michael D.
Issue Date2008
PublisherRoyal Society of Chemistry
CitationChemical Communications 37: 4460-4462 (2008)
AbstractReaction of the anionic cyanometallate chromophore [{Ru(CN)4}3(3-HAT)]6- with [MII(tren)]2+ complexes (M = ZnII, CuII) provides discrete tetradecanuclear clusters of formula [{MII(tren)(-CN)}11{Ru3(HAT)(CN)}]16+; the weak luminescence of the Ru3 chromophore is substantially enhanced in the presence of ZnII ions, whereas it is completely quenched when CuII centers are present.
Description3 pages, 2 figures.
Publisher version (URL)http://dx.doi.org/10.1039/b807364c
Appears in Collections:(IACT) Artículos
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