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Group 10 Metal Benzene-1,2-dithiolate Derivatives in the Synthesis of Coordination Polymers Containing Potassium Countercations

AuthorsCastillo, Oscar; Delgado, Esther; Gómez-García, Carlos J.; Hernández, Diego; Hernández, Elisa; Martín, Avelino; Martínez, José I. ; Zamora, Félix
Issue Date2-Oct-2017
PublisherAmerican Chemical Society
CitationInorganic Chemistry 56(19): 11810-11818 (2017)
AbstractThe use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SCHS)] (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K(μ-HO)][Ni(SCHS)]} and {[K(μ-HO)(thf)][K(μ-HO)(thf)][Pd(SCHS)]} by one-pot reactions of the corresponding d metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on σ,π interactions between potassium atoms and [M(SCHS)] (M = Ni, Pd) entities. In contrast, only σ interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K(μ-thf)][Pt(SCHS)]}.
Publisher version (URL)https://doi.org/10.1021/acs.inorgchem.7b01775
Identifiersdoi: 10.1021/acs.inorgchem.7b01775
e-issn: 1520-510X
issn: 0020-1669
Appears in Collections:(ICMM) Artículos
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