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Título: | Structural effects of LaNiO3 as electrocatalyst for the oxygen reduction reaction |
Autor: | Retuerto, María CSIC ORCID; González Pereira, Amaru; Pérez-Alonso, Francisco CSIC; Peña Jiménez, Miguel Antonio CSIC ORCID; García Fierro, José Luis CSIC ORCID; Alonso, J. A. CSIC ORCID; Fernández-Díaz, María Teresa; Pascual, Laura CSIC ORCID ; Rojas Muñoz, Sergio CSIC ORCID | Palabras clave: | ORR Particle size PND LaNiO3 Fuel cell |
Fecha de publicación: | abr-2017 | Editor: | Elsevier | Citación: | Applied Catalysis B - Environmental 203: 363-371 (2017) | Resumen: | LaNiO perovskite is a promising electrocatalyst for the oxygen reduction reaction (ORR). In this work we study the effects of several key structural and morphological features on the performance of LaNiO perovskites for the ORR. We have prepared a series of LaNiO oxides via soft chemistry and calcined the final materials at different temperatures from 500 to 1000 °C. With the aim of obtaining morphological and structural information relevant to their performance the prepared oxides have been thoroughly characterized by BET, Power Neutron Diffraction (PND), XRD, HRTEM, STEM-HAADF and XPS. We have analysed the effect of extrinsic (surface area and particle size) and intrinsic factors (formation of oxygen vacancies, Ni oxidation states and occupancy of the e levels) on the current densities and specific activity, respectively, of several samples of LaNiO. The catalysts with higher catalytic activity are those in which the perovskite structure is properly formed, but display high surface areas. | Versión del editor: | https://doi.org/10.1016/j.apcatb.2016.10.016 | URI: | http://hdl.handle.net/10261/187976 | DOI: | 10.1016/j.apcatb.2016.10.016 | ISSN: | 0926-3373 |
Aparece en las colecciones: | (ICMM) Artículos (ICP) Artículos |
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