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Chiral homogeneous and porous polymeric BINOL-phosphoric acids. Application for enantioselective cyclization of anthranylamides with aldehydes

AuthorsNavarro Crespo, Rodrigo ; Iglesias, Marta ; Corma, Avelino ; Monterde, Cristina; Sánchez, Félix
Issue Date2017
Citation13th European Congress on Catalysis (2017)
AbstractThe discovery of catalysts that efficiently facilitate stereocontrolled organic reactions is the keystone of asymmetric organic chemistry. Among the different useful systems, the catalysts based on the chiral BINOLs stand out considerably, Herein, we have easy prepared a series of new adamantyl-BINOLs and their application for cyclization of anthranylamides with high yields and enantioselectivities up to 99% in homogeneous solution or using these BINOLs incorporated into the framework of porous polymeric (PAFs) as heterogeneous catalysts.
DescriptionPoster presented at the 13th European Congress on Catalysis, held in Florence (Italy) on August 27-31, 2017.
Appears in Collections:(ICMM) Comunicaciones congresos
(IQOG) Comunicaciones congresos
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