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dc.contributor.authorConesa-Egea, Javieres_ES
dc.contributor.authorNogal, Noemíes_ES
dc.contributor.authorMartínez, José I.es_ES
dc.contributor.authorFernández-Moreira, Vanesaes_ES
dc.contributor.authorRodríguez-Mendoza, Ulises R.es_ES
dc.contributor.authorGonzález-Platas, Javieres_ES
dc.contributor.authorGómez-García, Carlos J.es_ES
dc.contributor.authorDelgado, Salomées_ES
dc.contributor.authorZamora, Félixes_ES
dc.contributor.authorAmo-Ochoa, Pilares_ES
dc.date.accessioned2019-07-29T08:00:46Z-
dc.date.available2019-07-29T08:00:46Z-
dc.date.issued2018-
dc.identifier.citationChemical Science 9(41): 8000-8010 (2018)es_ES
dc.identifier.issn2041-6520-
dc.identifier.urihttp://hdl.handle.net/10261/187055-
dc.description.abstractOne-pot reactions between CuI and methyl or methyl 2-amino-isonicotinate give rise to the formation of two coordination polymers (CPs) based on double zig-zag Cu2I2 chains. The presence of a NH2 group in the isonicotinate ligand produces different supramolecular interactions affecting the Cu-Cu distances and symmetry of the Cu2I2 chains. These structural variations significantly modulate their physical properties. Thus, both CPs are semiconductors and also show reversible thermo/mechanoluminescence. X-ray diffraction studies carried out under different temperature and pressure conditions in combination with theoretical calculations have been used to rationalize the multi-stimuli-responsive properties. Importantly, a bottom-up procedure based on fast precipitation leads to nanofibers of both CPs. The dimensions of these nanofibres enable the preparation of thermo/mechanochromic film composites with polyvinylidene difluoride. These films are tens of nanometers in thickness while being centimeters in length, representing smaller thicknesses so far reported for thin-film composites. This nanomaterial integration of CPs could represent a source of alternative nanomaterials for opto-electronic device fabrication.es_ES
dc.description.sponsorshipThe authors thank financial support from the Spanish Ministerio de Economía y Competitividad (MAT2016-77608-C3-1-P, MAT2016-75883-C2-2-P, MAT2010-20843-C02-01, MAT2016- 75586-C4-4-P, CTQ2016-75816-C2-1P). J. I. M. acknowledges the financial support by the “Ramón y Cajal” Program of MINECO (Grant RYC-2015-17730) and the EU via the ERCSynergy Program (Grant ERC-2013-SYG-610256 NANOCOSMOS). J. C. E. acknowledges the financial support by the “FPI-MINECO” Program of MINECO (Grant BES-2015-071534).es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.relationMINECO/ICTI2013-2016/MAT2016-77608-C3-1-Pes_ES
dc.relationMINECO/ICTI2013-2016/MAT2016-75883-C2-2-Pes_ES
dc.relationMINECO/ICTI2013-2016/MAT2016-75586-C4-4-Pes_ES
dc.relationMINECO/ICTI2013-2016/CTQ2016-75816-C2-1Pes_ES
dc.relationMINECO/ICTI2013-2016/RYC-2015-17730es_ES
dc.relationinfo:eu-repo/grantAgreement/ECFP7/610256es_ES
dc.relationMINECO/ICTI2013-2016/MDM-2014-0377-03es_ES
dc.relation.isversionofPublisher's versiones_ES
dc.rightsopenAccesses_ES
dc.titleSmart composite films of nanometric thickness based on copper–iodine coordination polymers. Toward sensorses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/c8sc03085e-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1039/C8SC03085Ees_ES
dc.identifier.e-issn2041-6539-
dc.rights.licensehttp://creativecommons.org/licenses/by-nc/3.0/es_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Research Counciles_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000781es_ES
dc.contributor.orcidMartínez, José I. [0000-0002-2086-8603]es_ES
dc.contributor.orcidGonzález-Platas, Javier [0000-0003-3339-2998]es_ES
dc.contributor.orcidGómez-García, Carlos J. [0000-0002-0015-577X]es_ES
dc.contributor.orcidZamora, Félix [0000-0001-7529-5120]es_ES
dc.contributor.orcidAmo-Ochoa, Pilar [0000-0002-1952-1020]es_ES
dc.identifier.pmid30450184-
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