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http://hdl.handle.net/10261/187055
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Conesa-Egea, Javier | es_ES |
dc.contributor.author | Nogal, Noemí | es_ES |
dc.contributor.author | Martínez, José I. | es_ES |
dc.contributor.author | Fernández-Moreira, Vanesa | es_ES |
dc.contributor.author | Rodríguez-Mendoza, Ulises R. | es_ES |
dc.contributor.author | González-Platas, Javier | es_ES |
dc.contributor.author | Gómez-García, Carlos J. | es_ES |
dc.contributor.author | Delgado, Salomé | es_ES |
dc.contributor.author | Zamora, Félix | es_ES |
dc.contributor.author | Amo-Ochoa, Pilar | es_ES |
dc.date.accessioned | 2019-07-29T08:00:46Z | - |
dc.date.available | 2019-07-29T08:00:46Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Chemical Science 9(41): 8000-8010 (2018) | es_ES |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/10261/187055 | - |
dc.description.abstract | One-pot reactions between CuI and methyl or methyl 2-amino-isonicotinate give rise to the formation of two coordination polymers (CPs) based on double zig-zag Cu2I2 chains. The presence of a NH2 group in the isonicotinate ligand produces different supramolecular interactions affecting the Cu-Cu distances and symmetry of the Cu2I2 chains. These structural variations significantly modulate their physical properties. Thus, both CPs are semiconductors and also show reversible thermo/mechanoluminescence. X-ray diffraction studies carried out under different temperature and pressure conditions in combination with theoretical calculations have been used to rationalize the multi-stimuli-responsive properties. Importantly, a bottom-up procedure based on fast precipitation leads to nanofibers of both CPs. The dimensions of these nanofibres enable the preparation of thermo/mechanochromic film composites with polyvinylidene difluoride. These films are tens of nanometers in thickness while being centimeters in length, representing smaller thicknesses so far reported for thin-film composites. This nanomaterial integration of CPs could represent a source of alternative nanomaterials for opto-electronic device fabrication. | es_ES |
dc.description.sponsorship | The authors thank financial support from the Spanish Ministerio de Economía y Competitividad (MAT2016-77608-C3-1-P, MAT2016-75883-C2-2-P, MAT2010-20843-C02-01, MAT2016- 75586-C4-4-P, CTQ2016-75816-C2-1P). J. I. M. acknowledges the financial support by the “Ramón y Cajal” Program of MINECO (Grant RYC-2015-17730) and the EU via the ERCSynergy Program (Grant ERC-2013-SYG-610256 NANOCOSMOS). J. C. E. acknowledges the financial support by the “FPI-MINECO” Program of MINECO (Grant BES-2015-071534). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (UK) | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-77608-C3-1-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-75883-C2-2-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-75586-C4-4-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2016-75816-C2-1P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/RYC-2015-17730 | es_ES |
dc.relation | info:eu-repo/grantAgreement/ECFP7/610256 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MDM-2014-0377-03 | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.title | Smart composite films of nanometric thickness based on copper–iodine coordination polymers. Toward sensors | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1039/c8sc03085e | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/C8SC03085E | es_ES |
dc.identifier.e-issn | 2041-6539 | - |
dc.rights.license | http://creativecommons.org/licenses/by-nc/3.0/ | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | European Research Council | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.contributor.orcid | Martínez, José I. [0000-0002-2086-8603] | es_ES |
dc.contributor.orcid | González-Platas, Javier [0000-0003-3339-2998] | es_ES |
dc.contributor.orcid | Gómez-García, Carlos J. [0000-0002-0015-577X] | es_ES |
dc.contributor.orcid | Zamora, Félix [0000-0001-7529-5120] | es_ES |
dc.contributor.orcid | Amo-Ochoa, Pilar [0000-0002-1952-1020] | es_ES |
dc.identifier.pmid | 30450184 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ISQCH) Artículos (ICMM) Artículos |
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smartsensor.pdf | 579,41 kB | Adobe PDF | Visualizar/Abrir |
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