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Título: | Synthesis of bimetallic Zr(Ti)-naphthalendicarboxylate MOFs and their properties as Lewis acid catalysis |
Autor: | Rasero-Almansa, Antonia M. CSIC; Sánchez, Félix CSIC ORCID | Fecha de publicación: | 2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | RSC Advances 6(108): 106790-106797 (2016) | Resumen: | Bimetallic Zr(Ti)-NDC based metal-organic frameworks (MOFs) have been prepared by incorporation of titanium(iv) into zirconium(iv)-NDC-MOFs (UiO family). The resulting materials maintain thermal (up to 500 °C), chemical and structural stability with respect to parent Zr-MOFs as can be deduced from XRD, N adsorption, FTIR and thermal analysis. The materials have been studied in Lewis acid catalyzed reactions, such as, domino Meerwein-Ponndorf-Verley (MPV) reduction-etherification of p-methoxybenzaldehyde with butanol, isomerization of α-pinene oxide and cyclization of citronellal. | Versión del editor: | http://doi.org/10.1039/C6RA23143H | URI: | http://hdl.handle.net/10261/186996 | DOI: | 10.1039/c6ra23143h | Identificadores: | doi: 10.1039/c6ra23143h e-issn: 2046-2069 |
Aparece en las colecciones: | (IQOG) Artículos (ICMM) Artículos |
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