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http://hdl.handle.net/10261/186785
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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Borja, Pilar | es_ES |
dc.contributor.author | Vicent, Cristian | es_ES |
dc.contributor.author | Baya, Miguel | es_ES |
dc.contributor.author | García Gómez, Hermenegildo | es_ES |
dc.contributor.author | Mata, José A. | es_ES |
dc.date.accessioned | 2019-07-24T12:30:44Z | - |
dc.date.available | 2019-07-24T12:30:44Z | - |
dc.date.issued | 2018 | - |
dc.identifier.citation | Green Chemistry 20(17): 4094-4101 (2018) | es_ES |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | http://hdl.handle.net/10261/186785 | - |
dc.description.abstract | We describe an unprecedented catalytic dehydrogenation of glucose by homogeneous catalysts. Iridium(III) complexes containing the fragment [Cp*Ir(NHC)]2+ (NHC = N-heterocyclic carbene ligand) are shown to be very active and highly selective catalysts for the dehydrogenation of glucose to gluconic acid and molecular hydrogen. Glucose is converted to gluconic acid at a catalyst loading of 2 mol%, at reflux in water, without additives and with a selectivity of over 95%. Experimental evidence obtained by 1H NMR spectroscopy and mass spectrometry (ESI/MS) reveals the formation of iridium coordinated to glucose and gluconic acid species. A plausible mechanism is proposed, based on the experimental evidence and supported by DFT calculations. | es_ES |
dc.description.sponsorship | The authors thank the MINECO (Severo Ochoa, CTQ2015-69153-C2-1-R, CTQ2015-69153-C2-2-R and CTQ2015-67461-P), Diputación General de Aragón (Grupo Consolidado E21) and Universitat Jaume I (P1.1B2015-09) for financial support. P. Borja thanks the Universitat Jaume I for a postdoctoral grant. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (UK) | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-69153-C2-1-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-69153-C2-2-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-67461-P | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.title | Iridium complexes catalysed the selective dehydrogenation of glucose to gluconic acid in water | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1039/C8GC01933A | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1039/C8GC01933A | es_ES |
dc.identifier.e-issn | 1463-9270 | - |
dc.rights.license | http://creativecommons.org/licenses/by/3.0/ | es_ES |
dc.contributor.funder | Universidad Jaime I | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Diputación General de Aragón | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004834 | es_ES |
dc.contributor.orcid | Borja, Pilar [0000-0001-6616-4399] | es_ES |
dc.contributor.orcid | Baya, Miguel [0000-0002-2492-625X] | es_ES |
dc.contributor.orcid | García, Hermenegildo [0000-0002-9664-493X] | es_ES |
dc.contributor.orcid | Mata, José A. [0000-0001-9310-2783] | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ISQCH) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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iridiumwater.pdf | 1,72 MB | Adobe PDF | Visualizar/Abrir |
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