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dc.contributor.authorJoven Sancho, Danieles_ES
dc.contributor.authorBaya, Migueles_ES
dc.contributor.authorMartín, Antonioes_ES
dc.contributor.authorMenjón, Babiles_ES
dc.date.accessioned2019-07-24T11:16:21Z-
dc.date.available2019-07-24T11:16:21Z-
dc.date.issued2018-
dc.identifier.citationChemistry - A European Journal 24(50): 13098–13101 (2018)es_ES
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10261/186752-
dc.description.abstractThe homoleptic silver(I) compound [PPh4 ][CF3 AgCF3 ] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4 ][Ag(CF3 )4 ] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their structural and spectroscopic properties have been experimentally established. Moreover, their electronic structures have been calculated by theoretical methods. The electronic structure of the oxidized species [Ag(CF3 )4 ]- provides a new case of ligand-field inversion caused by the CF3 ligands.es_ES
dc.description.sponsorshipThis work was supported by the Spanish MINECO/FEDER (Project CTQ2015-67461-P) and the Gobierno de Aragón and Fondo Social Europeo (Grupo de Referencia E17_17R: Química Inorgánica y de los Compuestos Organometálicos). D.J.-S. thanks the Spanish Ministerio de Economía, Industria y Competitividad for a grant (BES-2016-078732).es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.relationMINECO/ICTI2013-2016/CTQ2015-67461-Pes_ES
dc.rightsclosedAccesses_ES
dc.titleHomoleptic trifluoromethyl derivatives of AgI and AgIIIes_ES
dc.typeartículoes_ES
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201802960-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201802960es_ES
dc.identifier.e-issn1521-3765-
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderMinisterio de Economía, Industria y Competitividad (España)es_ES
dc.contributor.funderGobierno de Aragónes_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010067es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010198es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.pmid29981177-
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