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Title

Homoleptic trifluoromethyl derivatives of AgI and AgIII

AuthorsJoven Sancho, Daniel; Baya, Miguel ; Martín, Antonio ; Menjón, Babil
Issue Date2018
PublisherWiley-VCH
CitationChemistry - A European Journal 24(50): 13098–13101 (2018)
AbstractThe homoleptic silver(I) compound [PPh4 ][CF3 AgCF3 ] (1) provides a convenient entry to the homoleptic silver(III) derivative [PPh4 ][Ag(CF3 )4 ] (2). Once isolated as pure substances, these compounds exhibit marked thermal stabilities. Their structural and spectroscopic properties have been experimentally established. Moreover, their electronic structures have been calculated by theoretical methods. The electronic structure of the oxidized species [Ag(CF3 )4 ]- provides a new case of ligand-field inversion caused by the CF3 ligands.
Publisher version (URL)https://doi.org/10.1002/chem.201802960
URIhttp://hdl.handle.net/10261/186752
DOI10.1002/chem.201802960
ISSN0947-6539
E-ISSN1521-3765
Appears in Collections:(ISQCH) Artículos
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