English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/186580
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Efficient gold(I) acyclic diaminocarbenes for the synthesis of propargylamines and indolizines

AuthorsAliaga-Lavrijsen, Mélanie; Herrera, Raquel P.; Villacampa, M. Dolores ; Gimeno, M. Concepción
Issue Date2018
PublisherAmerican Chemical Society
CitationACS Omega 3(8): 9805-9813 (2018)
AbstractMononuclear gold(I) acyclic diaminocarbenes (ADCs) were prepared by the reaction of 1,2-cyclohexanediamine with the corresponding isocyanide complexes [AuCl(CNR)] (R = Cy, tBu). The three-component coupling of aldehydes, amines, and alkynes was investigated by using these gold(I) ADC complexes. The new gold(I) metal complexes are highly efficient catalysts for the synthesis of propargylamines and indolizines in the absence of solvent and in mild conditions. This method affords the corresponding final products with excellent yields in short reaction times. Additionally, chiral gold(I) complexes with ADCs have been prepared and tried in the enantioselective synthesis of propargylamines.
Publisher version (URL)https://doi.org/10.1021/acsomega.8b01352
URIhttp://hdl.handle.net/10261/186580
DOI10.1021/acsomega.8b01352
E-ISSN2470-1343
Appears in Collections:(ISQCH) Artículos
Files in This Item:
File Description SizeFormat 
efficindoli.pdf1,19 MBAdobe PDFView/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.