SrMnO3 thermochromic behavior governed by size-dependent structural distortions

Abstract

The influence of particle size in both the structure and thermochromic behavior of 4H-SrMnO related perovskite is described. Microsized SrMnO suffers a structural transition from hexagonal (P6/mmc) to orthorhombic (C222) symmetry at temperature close to 340 K. The orthorhombic distortion is due to the tilting of the corner-sharing MnO units building the 4H structural type. When temperature decreases, the distortion becomes sharper reaching its maximal degree at ∼125 K. These structural changes promote the modification of the electronic structure of orthorhombic SrMnO phase originating the observed color change. nano-SrMnO adopts the ideal 4H hexagonal structure at room temperature, the orthorhombic distortion being only detected at temperature below 170 K. A decrease in the orthorhombic distortion degree, compared to that observed in the microsample, may be the reason why a color change is not observed at low temperature (77 K).