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Título: | Chiral periodic mesoporous copper(II) bis(oxazoline) phenylene-silica: A highly efficient and reusable asymmetric heterogeneous catalyst |
Autor: | Lourenço, Mirtha A. O.; Carneiro, Liliana; Mayoral, Álvaro CSIC ORCID; Díaz Carretero, Isabel CSIC ORCID ; Silva, Ana R.; Ferreira, Paula | Palabras clave: | Asymmetric catalysis Co-condensation Periodic mesoporous organosilicas Heterogeneous catalysis Homogeneous catalysis |
Fecha de publicación: | dic-2014 | Editor: | Elsevier | Citación: | Journal of Catalysis 320: 63-69 (2014) | Resumen: | We describe the preparation of an effective and reusable heterogeneous asymmetric catalyst. A novel chiral periodic mesoporous phenylene–silica containing high density of bis(oxazoline) moieties is prepared by co-condensation method with 1,4-bis(triethoxysilyl)benzene. After copper(II) coordination, the material is extremely efficient on the kinetic resolution of the 1,2-diphenylethane-1,2-diol with persistent high enantioselectivities (91 - > 99%) and yields (46–43% in maximum 50% resolution) at least for five consecutive cycles. Characterization of the material after the catalytic experiments showed that the heterogeneous catalyst was very robust keeping the integrity of the structure. | Versión del editor: | https://doi.org/10.1016/j.jcat.2014.09.017 | URI: | http://hdl.handle.net/10261/186139 | DOI: | 10.1016/j.jcat.2014.09.017 | ISSN: | 0021-9517 | E-ISSN: | 1090-2694 |
Aparece en las colecciones: | (ICP) Artículos |
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