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Title

Surface-Supported Robust 2D Lanthanide-Carboxylate Coordination Networks

AuthorsUrgel, José I.; Cirera, Borja; Wang, Yang; Auwärter, Willi; Otero, Roberto; Gallego, José M. ; Alcamí, Manuel; Klyatskaya, Svetlana; Ruben, Mario; Martín, Fernando; Miranda, Rodolfo ; Ecija, David; Barth, Johannes V.
KeywordsCoordination networks, self‐assembly
Lanthanides
Metal-organic coordination networks
Surface coordination chemistry
Issue Date16-Dec-2015
PublisherJohn Wiley & Sons
CitationSmall 11(47): 6358-6364 (2015)
AbstractLanthanide-based metal-organic compounds and architectures are promising systems for sensing, heterogeneous catalysis, photoluminescence, and magnetism. Herein, the fabrication of interfacial 2D lanthanide-carboxylate networks is introduced. This study combines low- and variable-temperature scanning tunneling microscopy (STM) and X-ray photoemission spectroscopy (XPS) experiments, and density functional theory (DFT) calculations addressing their design and electronic properties. The bonding of ditopic linear linkers to Gd centers on a Cu(111) surface gives rise to extended nanoporous grids, comprising mononuclear nodes featuring eightfold lateral coordination. XPS and DFT elucidate the nature of the bond, indicating ionic characteristics, which is also manifest in appreciable thermal stability. This study introduces a new generation of robust low-dimensional metallosupramolecular systems incorporating the functionalities of the f-block elements.
Publisher version (URL)https://doi.org/10.1002/smll.201502761
URIhttp://hdl.handle.net/10261/185180
Identifiersdoi: 10.1002/smll.201502761
e-issn: 1613-6829
issn: 1613-6810
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