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2D-cadmium MOF and gismondine-like zinc coordination network based on the N-(2-tetrazolethyl)-4′-glycine linker

AuthorsSalinas-Castillo, Alfonso; Calahorro, Antonio J.; Briones, David; Fairen-Jiménez, David; Gándara Barragán, Felipe ; Mendicute-Fierro, Claudio; Seco, José M.; Pérez-Mendoza, Manuel; Fernández, Belén; Rodríguez-Diéguez, Antonio
Issue Date25-Feb-2015
PublisherRoyal Society of Chemistry (UK)
CitationNew Journal of Chemistry 39(5): 3982-3986 (2015)
AbstractWe have designed and synthesized two new metal–organic-frameworks (MOFs) using the novel N-(2-tetrazolethyl)-4′-glycine spacer (TeGly)2−. We report the in situ formation of cadmium- and zinc-based MOFs using hydrothermal routes. The cadmium-based MOF shows a bi-dimensional network with luminescence emission while the zinc-based MOF exhibits a three-dimensional structure with gismondine topology and intense blue-greenish photoluminescence emission at room temperature in the solid state. In addition, the porosity of the Zn-based MOF has been fully characterized using a combination of computational methods and experimental techniques.
Publisher version (URL)http://doi.org/10.1039/C5NJ00011D
Identifiersdoi: 10.1039/c5nj00011d
e-issn: 1369-9261
issn: 1144-0546
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