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Metal-organic scandium framework: Useful material for hydrogen storage and catalysis

AuthorsPerles, Josefina ; Iglesias, Marta ; Martín-Luengo, María Ángeles ; Monge, M. Ángeles ; Ruiz-Valero, Caridad; Snejko, Natalia
Issue Date22-Oct-2005
PublisherAmerican Chemical Society
CitationChemistry of Materials 17(23): 5837-5842 (2005)
AbstractThe 3D polymeric terephthalate of scandium has been synthesized and its structure solved by single-crystal XRD. It was obtained as a single phase and characterized and tested as a hydrogen and nitrogen adsorbent and heterogeneous catalyst as a redox agent in the oxidation of sulfides. The compound shows a BET area of 721 m2 g-1 with a high CBET = 7000. The high chemical and thermal stability and excellent hydrogen sorption properties make this compound a useful material for hydrogen storage.
Publisher version (URL)https://doi.org/10.1021/cm051362e
Appears in Collections:(ICMM) Artículos
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