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dc.contributor.authorVolbeda, A.-
dc.contributor.authorAmara, Patricia-
dc.contributor.authorIannello, Marina-
dc.contributor.authorLópez de Lacey, Antonio-
dc.contributor.authorCavazza, Christine-
dc.contributor.authorFontecilla-Camps, Juan Carlos-
dc.date.accessioned2019-05-31T09:20:16Z-
dc.date.available2019-05-31T09:20:16Z-
dc.date.issued2013-
dc.identifier.citationChemical Communications 49(63): 7061-7063 (2013)-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10261/183008-
dc.description.abstractThis study shows how the NiFeSe site of an anaerobically purified O2-resistant hydrogenase reacts with air to give a seleninate as the first product. Less oxidized states of the active site are readily reduced in the presence of X-rays. Reductive enzyme activation requires an efficient pathway for water escape.-
dc.description.sponsorshipWe thank the Commissariat à l'Energie Atomique et aux Energies Alternatives (CEA) and the Centre National de la Recherche Scientifique (CNRS) for institutional funding, the Agence Nationale de la Recherche for Grant ANR-08-PANH-008, the Spanish MINECO for funding project CTQ2012-32448 and the staff of the synchrotron beamlines BM30A, ID14-1 and ID23-1 for help with X-ray data collections.-
dc.publisherRoyal Society of Chemistry (UK)-
dc.rightsclosedAccess-
dc.titleStructural foundations for the O2 resistance of Desulfomicrobium baculatum [NiFeSe]-hydrogenase-
dc.typeartículo-
dc.identifier.doi10.1039/c3cc43619e-
dc.relation.publisherversionhttps://doi.org/10.1039/C3CC43619E-
dc.identifier.e-issn1364-548X-
dc.date.updated2019-05-31T09:20:16Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderCentre National de la Recherche Scientifique (France)-
dc.contributor.funderAgence Nationale de la Recherche (France)-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderCommissariat à l'Ènergie Atomique et aux Ènergies Alternatives (France)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100006489es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100001665es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004794es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.grantfulltextnone-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextNo Fulltext-
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