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Structural foundations for the O2 resistance of Desulfomicrobium baculatum [NiFeSe]-hydrogenase

AuthorsVolbeda, A.; Amara, Patricia; Iannello, Marina; Lacey, Antonio L. de; Cavazza, Christine; Fontecilla-Camps, Juan Carlos
Issue Date2013
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 49(63): 7061-7063 (2013)
AbstractThis study shows how the NiFeSe site of an anaerobically purified O2-resistant hydrogenase reacts with air to give a seleninate as the first product. Less oxidized states of the active site are readily reduced in the presence of X-rays. Reductive enzyme activation requires an efficient pathway for water escape.
Publisher version (URL)https://doi.org/10.1039/C3CC43619E
Appears in Collections:(ICP) Artículos
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