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Title

Tetradecanuclearity in 3d–4f chemistry: relaxation and magnetocaloric effects in [NiII6LnIII8] species

AuthorsCanaj, Angelos B.; Kalofolias, Dimitris A.; Siczek, Milosz; Lis, Tadeusz; McNab, Robbie; Lorusso, Giulia; Inglis, Ross; Evangelisti, Marco CSIC ORCID ; Milios, Constantinos J.
Issue Date2017
PublisherRoyal Society of Chemistry (UK)
CitationDalton Transactions 46(11): 3449-3452 (2017)
AbstractThe employment of 2-amino-isobutyric acid, Haib, and 2-hydroxy-1-naphthaldehyde, Hnaphth, in NiII/LnIII chemistry has led to the isolation and characterization of two new isostructural 3d–4f tetradecanuclear [NiII6LnIII8] clusters (Ln = GdIII, DyIII), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals, and the Gd analogue showing interesting magnetocaloric properties.
Publisher version (URL)https://doi.org/10.1039/C7DT00102A
URIhttp://hdl.handle.net/10261/182436
DOI10.1039/C7DT00102A
ISSN1477-9226
E-ISSN1477-9234
Appears in Collections:(ICMA) Artículos




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