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Magnetic interaction between d1 [MOR4]− units of molybdenum and tungsten

AuthorsGarcía-Monforte, M. Ángeles ; Alonso, Pablo J.; Arauzo, Ana B.; Baya, Miguel ; Luis, Fernando; Martín, Antonio ; Menjón, Babil ; Rillo, Conrado
Issue Date2017
PublisherTrans Tech Publications
CitationSolid State Phenomena 257: 223-226 (2017)
AbstractFive-coordinate oxo-derivatives [NBu 4 ][MO(C 6 F 5 ) 4 ] (1) have been prepared for the heavier Group 6 elements: 1-Mo and 1-W. The magnetic properties of that salts have been studied by a combination of Electron paramagnetic resonance (EPR), calorimetric and magnetochemical techniques, pointing out the existence of weak ferromagnetic interactions. These have been correlated with the arrangement of the magnetic units in the crystal.
Publisher version (URL)https://doi.org/10.4028/www.scientific.net/SSP.257.223
Appears in Collections:(ICMA) Artículos
(ISQCH) Artículos
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