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Chiral supramolecular organization from a sheetlike achiral gel: a study of chiral photoinduction

AuthorsRoyes, Jorge; Polo, Víctor; Uriel, Santiago; Oriol, Luis; Piñol, Milagros; Tejedor, Rosa M.
Issue Date2017
PublisherRoyal Society of Chemistry (UK)
CitationPhysical Chemistry Chemical Physics 19(21): 13622-13628 (2017)
AbstractChiral photoinduction in a photoresponsive gel based on an achiral 2D architecture with high geometric anisotropy and low roughness has been investigated. Circularly polarized light (CPL) was used as a chiral source and an azobenzene chromophore was employed as a chiral trigger. The chiral photoinduction was studied by evaluating the preferential excitation of enantiomeric conformers of the azobenzene units. Crystallographic data and density functional theory (DFT) calculations show how chirality is transferred to the achiral azomaterials as a result of the combination of chiral photochemistry and supramolecular interactions. This procedure could be applied to predict and estimate chirality transfer from a chiral physical source to a supramolecular organization using different light-responsive units.
Publisher version (URL)https://doi.org/10.1039/C7CP01739A
Appears in Collections:(ICMA) Artículos
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