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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/18173
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dc.contributor.authorMolina Orden, María Teresa-
dc.contributor.authorNavarro, Cristina-
dc.contributor.authorMoreno, Ana-
dc.contributor.authorCsákÿ, Aurelio G.-
dc.date.accessioned2009-10-29T12:05:57Z-
dc.date.available2009-10-29T12:05:57Z-
dc.date.issued2009-10-29T12:05:57Z-
dc.identifier.citationOrganic Letters 2009, 11, 4938-4941-
dc.identifier.issn1523-7060-
dc.identifier.urihttp://hdl.handle.net/10261/18173-
dc.description.abstractThe first examples of the direct arylation of benzo-fused 1,4-quinones by the dicationic Pd(II)-catalyzed addition of arylboronic acids are reported. The addition reaction is carried out under very mild conditions (dioxane-H2O, rt, open air atmosphere) and is tolerant of free OH groups. In addition, the reaction shows high regioselectivity when using nonsymmetrical quinones as starting materials.en_US
dc.description.sponsorshipProjects UCM-BSCH GR58/08-910815 and CTQ2006-15279-C03-01 (both to A.G.C.), and SAF2006- 04698 (to M.T.M.), are gratefully acknowledged for financial support.en_US
dc.format.extent24064 bytes-
dc.format.mimetypeapplication/msword-
dc.language.isoengen_US
dc.rightsopenAccessen_US
dc.subjectArylationen_US
dc.subjectJugloneen_US
dc.subjectNatural productsen_US
dc.subjectArylboronic acidsen_US
dc.subjectAnthraquinones-
dc.subjectNaphthoquinones-
dc.subjectPalladium catalysis-
dc.subjectLigand effects-
dc.titleArylation of Benzo-Fused 1,4-Quinones by the Addition of Boronic Acids under Dicationic Pd(II)-Catalysisen_US
dc.typeartículoen_US
dc.identifier.doi10.1021/ol902084g-
dc.description.peerreviewedPeer revieweden_US
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.grantfulltextopen-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
item.languageiso639-1en-
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