English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/181414
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Title

Intraframework migration of tetrahedral atoms in a zeolite

AuthorsShin, Jiho; Ahn, Nak Ho; Camblor, Miguel Ángel ; Cho, Sung June; Hong, Suk Bong
KeywordsDisorder‐to‐order process
Intraframework migration
Solid‐state reactions
Tetrahedral atoms
Zeolites
Issue Date18-Aug-2014
PublisherJohn Wiley & Sons
CitationAngewandte Chemie International Edition 53(34): 8949-8952 (2014)
AbstractThe transformation from a disordered into an ordered version of the zeolite natrolite occurs on prolonged heating of this material in the crystallizing medium, but not if the mother liquor is replaced by water or an alkaline solution. This process occurs for both aluminosilicate and gallosilicate analogues of natrolite. In cross experiments, the disordered Al-containing (or Ga-containing) analogue is heated while in contact with the mother liquor of the opposite analogue, that is, the Ga-containing (or Al-containing) liquor. Therefore, strong evidence for the mechanism of the ordering process was obtained, which was thus proposed to proceed by intraframework migration of tetrahedral atoms without diffusion along the pores. Migration is first triggered, then fuelled by surface rearrangement through reactions with the mother liquor, and stops when an almost fully ordered state is attained. Classical dissolution-recrystallization and Ostwald ripening processes do not appear to be relevant for this phase transformation.
Publisher version (URL)http://doi.org/10.1002/anie.201404379
URIhttp://hdl.handle.net/10261/181414
DOI10.1002/anie.201404379
ISSN1433-7851
E-ISSN1521-3773
Appears in Collections:(ICMM) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.