English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/181020
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Encapsulation of a CrIII single-ion magnet within an feII spin-crossover supramolecular host

AuthorsDarawsheh, Mohanad; Barrios, L. A.; Roubeau, Olivier; Teat, Simon J.; Aromí, Guillem
KeywordsHost-guest chemistry
Single-ion magnets
Spin crossover
Spintronic devices
Issue Date2018
PublisherWiley-VCH
CitationAngewandte Chemie International Edition 57(41): 13509-13513 (2018)
AbstractSingle functional molecules are regarded as future components of nanoscale spintronic devices. Supramolecular coordination chemistry provides unlimited resources to implement multiple functions to individual molecules. A novel coordination [Fe2 ] helicate exhibiting spin-crossover is demonstrated to be ideally suited to encapsulate a [Cr(ox)3 ]3- complex anion (ox=oxalate), unveiling for the first-time single ion slow relaxation of the magnetization for this metal. A possibility of tuning the dynamics of this relaxation as well as the performance of the CrIII center as qubit arises from the observation that metastable high spin FeII centers from the host can be generated by irradiation with green light at low temperature.
URIhttp://hdl.handle.net/10261/181020
DOI10.1002/anie.201807256
ISSN1433-7851
E-ISSN1521-3773
Appears in Collections:(ICMA) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf59,24 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.