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http://hdl.handle.net/10261/18100
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Castro-Rodrigo, Ruth | - |
dc.contributor.author | Esteruelas, Miguel A. | - |
dc.contributor.author | Fuertes, Sara | - |
dc.contributor.author | López, Ana M. | - |
dc.contributor.author | López, Fernando | - |
dc.contributor.author | Mascareñas, José L. | - |
dc.contributor.author | Mozo, Silvia | - |
dc.contributor.author | Oñate, Enrique | - |
dc.contributor.author | Saya, Lucía | - |
dc.contributor.author | Villarino, Lara | - |
dc.date.accessioned | 2009-10-27T13:09:03Z | - |
dc.date.available | 2009-10-27T13:09:03Z | - |
dc.date.issued | 2009-10-09 | - |
dc.identifier.citation | Journal of the American Chemical Society 131(43): 15572-15573 (2009) | en_US |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.uri | http://hdl.handle.net/10261/18100 | - |
dc.description.abstract | Alkylidenecyclopropanes containing a chelation assistant at the terminal carbon atom of the olefinic moiety undergo an Os- or Ru-promoted ring expansion reaction to afford metal cyclobutylidene derivatives. The process occurs through a novel mechanism that implies a 1,2-migration of a CH2 group of the three-membered ring from an olefinic carbon atom to the other one. It takes place, without direct participation of the metal, on a metallaheterocyclopentene intermediate which is generated from an η2-methylenecyclopropane species stabilized by coordination of the chelation assistant. | en_US |
dc.description.sponsorship | Financial support from the Spanish MICINN (Projects CTQ2008-00810, SAF2007-61015 and Consolider Ingenio 2010 (CSD2007-00006)), Diputacin General de Aragón (E35), and Xunta de Galicia (GRC2006/132). L.S. and L.B. thank MICINN and Xunta de Galicia for their grants. | en_US |
dc.format.extent | 579917 bytes | - |
dc.format.mimetype | image/jpeg | - |
dc.language.iso | eng | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | closedAccess | en_US |
dc.subject | Osmium | en_US |
dc.subject | Ruthenium | en_US |
dc.subject | Cyclobutylidene Complexes | en_US |
dc.subject | Alkylidenecyclopropanes | en_US |
dc.title | Formation of osmium− and ruthenium−cyclobutylidene complexes by ring expansion of alkylidenecyclopropanes | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1021/ja904893j | - |
dc.description.peerreviewed | Peer reviewed | en_US |
dc.relation.publisherversion | http://dx.doi.org/10.1021/ja904893j | en_US |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.cerifentitytype | Publications | - |
Aparece en las colecciones: | (IQOG) Artículos (ICMA) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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