Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/180895
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Moreira, Rui | es_ES |
dc.contributor.author | Ochoa, Elba | es_ES |
dc.contributor.author | Pinilla Ibarz, José Luis | es_ES |
dc.contributor.author | Portugal, António | es_ES |
dc.contributor.author | Suelves Laiglesia, Isabel | es_ES |
dc.date.accessioned | 2019-05-03T12:18:03Z | - |
dc.date.available | 2019-05-03T12:18:03Z | - |
dc.date.issued | 2018-03-22 | - |
dc.identifier.citation | Catalysts 8(4): 127 (2018) | es_ES |
dc.identifier.issn | 2073-4344 | - |
dc.identifier.uri | http://hdl.handle.net/10261/180895 | - |
dc.description | 2 Tablas,7 Figuras, 14 Páginas. | es_ES |
dc.description.abstract | In this work, a Mo2C catalyst that was supported on commercial carbon nanofibers (CNF) was synthetized and tested in the hydrodeoxygenation (HDO) of guaiacol. The effects of operating conditions (temperature and pressure) and reaction time (2 and 4 h) on the conversion of guaiacol and products selectivity were studied. The major reaction products were cresol and phenol, followed by xylenols and toluene. The use of more severe operating conditions during the HDO of guaiacol caused a diversification in the reaction pathways, and consequently in the selectivity to products. The formation of phenol may have occurred by demethylation of guaiacol, followed by dehydroxylation of catechol, together with other reaction pathways, including direct guaiacol demethoxylation, and demethylation of cresols. X-ray diffraction (XRD) analysis of spent catalysts did not reveal any significant changes as compared to the fresh catalyst. | es_ES |
dc.description.sponsorship | This work was funded by FEDER and the Spanish Economy and Competitiveness Ministry (MINECO) (ENE2014-52189-C02-01-R and ENE2017-83854-R). Elba Ochoa thanks for the award of her PhD under the frame of this project. J.L.P. thanks MINECO for his Ramon y Cajal research contract (RYC-2013-12494). Rui Moreira is extremely grateful to ICB-CSIC for partially financing living costs during his short term mission. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Molecular Diversity Preservation International | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2014-52189-C02-01-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-83854-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/RYC-2013-12494 | es_ES |
dc.relation.isversionof | Publisher's version | es_ES |
dc.rights | openAccess | es_ES |
dc.subject | Hydrodeoxygenation | es_ES |
dc.subject | Molybdenum carbide catalyst | es_ES |
dc.subject | Carbon nanofibers supported catalysts | es_ES |
dc.title | Liquid-phase hydrodeoxygenation of guaiacol over Mo2C supported on commercial CNF. Effects of operating conditions on conversion and product selectivity | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.3390/catal8040127 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.3390/catal8040127 | es_ES |
dc.identifier.e-issn | 2073-4344 | - |
dc.rights.license | https://creativecommons.org/licenses/by/4.0/ | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | CSIC - Instituto de Carboquímica (ICB) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.contributor.orcid | Pinilla Ibarz, José Luis [0000-0002-8304-9656] | es_ES |
dc.contributor.orcid | Portugal, António [0000-0002-7520-4767] | es_ES |
dc.contributor.orcid | Suelves Laiglesia, Isabel [0000-0001-8437-2204] | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (ICB) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Catalysts_2018,8,127.pdf | Artículo principal | 6,58 MB | Adobe PDF | Visualizar/Abrir |
catalysts-08-00127-s001.pdf | Información suplementaria | 239,75 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
28
checked on 17-abr-2024
WEB OF SCIENCETM
Citations
26
checked on 23-feb-2024
Page view(s)
299
checked on 22-abr-2024
Download(s)
234
checked on 22-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
Este item está licenciado bajo una Licencia Creative Commons