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dc.contributor.authorHernández-Guerra, Daniel-
dc.contributor.authorRodríguez Morales, María S.-
dc.contributor.authorSuárez, Ernesto-
dc.date.accessioned2019-04-12T08:05:39Z-
dc.date.available2019-04-12T08:05:39Z-
dc.date.issued2014-08-
dc.identifierdoi: 10.1002/ejoc.201402387-
dc.identifierissn: 1434-193X-
dc.identifiere-issn: 1099-0690-
dc.identifier.citationEuropean Journal of Organic Chemistry 2014(23): 5033-5055 (2014)-
dc.identifier.urihttp://hdl.handle.net/10261/179992-
dc.description.abstractA direct approach to β‐iodophosphonates and β‐iodophosphine oxides from 2,3‐dideoxy‐3‐phosphoryl carbohydrate derivatives has been achieved by using the anomeric alkoxyl radical 1,2‐fragmentation protocol. The reaction has been conducted on carbohydrate derivatives under mild conditions with (diacetoxyiodo)benzene and molecular iodine. Subsequent dehydroiodination afforded the corresponding vinylphosphonates and vinylphosphine oxides.-
dc.description.sponsorshipThis work was supported by the Ministerio de Economía y Competitividad (Investigation Programs, grant numbers CTQ2010‐18244 and CTQ2007‐67492) and by the Gobierno de Canarias (grant numbers SolSub20081000192 and ProID20100088). D.H.‐G. thanks the Ministerio de Economía y Competitividad for a fellowship.-
dc.publisherWiley-VCH-
dc.publisherChemPubSoc Europe-
dc.rightsclosedAccess-
dc.subjectCarbohydrates-
dc.subjectPhosphorus-
dc.subjectCycli­zation-
dc.subjectRadicals-
dc.subjectSynthetic methods-
dc.titleFragmentation of carbohydrate anomeric alkoxyl radicals: Synthesis of chiral polyhydroxylated β-iodo- and alkenylorganophosphorus(V) compounds-
dc.typeartículo-
dc.identifier.doi10.1002/ejoc.201402387-
dc.relation.publisherversionhttps://doi.org/10.1002/ejoc.201402387-
dc.date.updated2019-04-12T08:05:39Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderGobierno de Canarias-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.openairetypeartículo-
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