Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/179992
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Fragmentation of carbohydrate anomeric alkoxyl radicals: Synthesis of chiral polyhydroxylated β-iodo- and alkenylorganophosphorus(V) compounds |
Autor: | Hernández-Guerra, Daniel CSIC; Rodríguez Morales, María S. CSIC ORCID ; Suárez, Ernesto CSIC ORCID | Palabras clave: | Carbohydrates Phosphorus Cyclization Radicals Synthetic methods |
Fecha de publicación: | ago-2014 | Editor: | Wiley-VCH ChemPubSoc Europe |
Citación: | European Journal of Organic Chemistry 2014(23): 5033-5055 (2014) | Resumen: | A direct approach to β‐iodophosphonates and β‐iodophosphine oxides from 2,3‐dideoxy‐3‐phosphoryl carbohydrate derivatives has been achieved by using the anomeric alkoxyl radical 1,2‐fragmentation protocol. The reaction has been conducted on carbohydrate derivatives under mild conditions with (diacetoxyiodo)benzene and molecular iodine. Subsequent dehydroiodination afforded the corresponding vinylphosphonates and vinylphosphine oxides. | Versión del editor: | https://doi.org/10.1002/ejoc.201402387 | URI: | http://hdl.handle.net/10261/179992 | DOI: | 10.1002/ejoc.201402387 | Identificadores: | doi: 10.1002/ejoc.201402387 issn: 1434-193X e-issn: 1099-0690 |
Aparece en las colecciones: | (IPNA) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
14
checked on 27-mar-2024
WEB OF SCIENCETM
Citations
13
checked on 25-feb-2024
Page view(s)
227
checked on 28-mar-2024
Download(s)
29
checked on 28-mar-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.