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Título: | Teydealdehyde, a C23-terpenoid from transformed root cultures of Nepeta teydea |
Autor: | Fraga, Braulio M. CSIC; Díaz, Carmen E. CSIC ORCID ; Amador, Leonardo J. CSIC | Palabras clave: | Teydealdehyde Nepeta Teydea Transformed Root Cultures Degraded Triterpene |
Fecha de publicación: | 7-ago-2013 | Editor: | Elsevier | Citación: | Tetrahedron Letters 54(32): 4337-4338 (2013) | Resumen: | Teydealdehyde, a C23-terpenoid with a new carbon skeleton, has been isolated from Nepeta teydea root cultures transformed by Agrobacterium rhizogenes. Its structure, determined from HRMS, 1D and 2D NMR data, shows four cycles with a five membered A ring deoxygenated at C-3 and with a C-2 aldehyde group at C-1. The B-, C- and D-rings are similar to those of the oleanane, ursane and lupane triterpenes, but the last cycle contains an α,β-unsaturated ketone as the result of a ring E biodegradation process of a pentacyclic triterpene precursor. | Versión del editor: | https://doi.org/10.1016/j.tetlet.2013.06.031 | URI: | http://hdl.handle.net/10261/179035 | DOI: | 10.1016/j.tetlet.2013.06.031 | Identificadores: | doi: 10.1016/j.tetlet.2013.06.031 issn: 0040-4039 |
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