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Title

Teydealdehyde, a C23-terpenoid from transformed root cultures of Nepeta teydea

AuthorsFraga, Braulio M. CSIC; Díaz, Carmen E. CSIC ORCID ; Amador, Leonardo J.
KeywordsTeydealdehyde
Nepeta Teydea
Transformed Root Cultures
Degraded Triterpene
Issue Date7-Aug-2013
PublisherElsevier
CitationTetrahedron Letters 54(32): 4337-4338 (2013)
AbstractTeydealdehyde, a C23-terpenoid with a new carbon skeleton, has been isolated from Nepeta teydea root cultures transformed by Agrobacterium rhizogenes. Its structure, determined from HRMS, 1D and 2D NMR data, shows four cycles with a five membered A ring deoxygenated at C-3 and with a C-2 aldehyde group at C-1. The B-, C- and D-rings are similar to those of the oleanane, ursane and lupane triterpenes, but the last cycle contains an α,β-unsaturated ketone as the result of a ring E biodegradation process of a pentacyclic triterpene precursor.
Publisher version (URL)https://doi.org/10.1016/j.tetlet.2013.06.031
URIhttp://hdl.handle.net/10261/179035
DOIhttp://dx.doi.org/10.1016/j.tetlet.2013.06.031
Identifiersdoi: 10.1016/j.tetlet.2013.06.031
issn: 0040-4039
Appears in Collections:(IPNA) Artículos
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