Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/178851
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dc.contributor.authorHernández-Guerra, Daniel-
dc.contributor.authorRodríguez Morales, María S.-
dc.contributor.authorSuárez, Ernesto-
dc.date.accessioned2019-03-29T11:00:57Z-
dc.date.available2019-03-29T11:00:57Z-
dc.date.issued2013-01-09-
dc.identifierdoi: 10.1021/ol302939z-
dc.identifierissn: 1523-7060-
dc.identifiere-issn: 1523-7052-
dc.identifier.citationOrganic Letters 15(2): 250-253 (2013)-
dc.identifier.urihttp://hdl.handle.net/10261/178851-
dc.description.abstractA new general methodology for the synthesis of chiral vinylphosphonate and vinylphosphine oxide carbohydrate derivatives has been developed using the anomeric alkoxyl radical fragmentation reaction as the key step. The synthetic sequence proceeded via β-iodophosphonate and β-iodophosphine oxide intermediates, which may be interesting synthons for the introduction of phosphorus into organic molecules. These vinylphosphonates could be easily transformed into 2-methylene-1-phosphapentofuranoses (3-methylene-1,2-oxaphospholanes) and β-aminophosphonates, isosteres of biologically active α-methylene-γ-lactones and β-amino acids, respectively.-
dc.description.sponsorshipThis work was supported by the Investigation Programs (CTQ2010-18244 and CTQ2007-67492) of the Ministerio de Economía y Competitividad and (SolSub20081000192 and ProID20100088) of the Gobierno de Canarias. D.H.-G. thanks the Ministerio de Economía y Competitividad for a fellowship.-
dc.language.isoeng-
dc.publisherAmerican Chemical Society-
dc.rightsclosedAccess-
dc.titleSynthesis of chiral β-iodo-and vinylorganophosphorus(V) compounds by fragmentation of carbohydrate anomeric alkoxyl radicals-
dc.typeartículo-
dc.identifier.doi10.1021/ol302939z-
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/ol302939z-
dc.date.updated2019-03-29T11:00:57Z-
dc.description.versionPeer Reviewed-
dc.contributor.funderGobierno de Canarias-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.fulltextNo Fulltext-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
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