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Título: | New strategy toward the diverted synthesis of oxidized abietane diterpenes via oxidation of 6,7-dehydroferruginol methyl ether with dimethyldioxirane |
Autor: | Cordova-Guerrero, I.; San Andrés, Lucía; Leal-Orozco, Alma E.; Padrón, José M.; Cornejo-Bravo, J.M.; León, Francisco CSIC ORCID | Palabras clave: | Sugiol Dimethyldioxirane Alkene oxidation Ferruginol |
Fecha de publicación: | 14-ago-2013 | Editor: | Elsevier | Citación: | Tetrahedron Letters 54(33): 4479-4482 (2013) | Resumen: | A series of oxidized abietane diterpenes have been synthesized from 8,11,13-abietanotriene. The reaction of 6,7-dehydroferruginol methyl ether with dimethyldioxirane (DMDO) was carried out under various conditions. In all cases, the oxidation of positions C-6 and C-7 were observed with high selectivity when DMDO was used. When some reaction conditions, such as temperature and time were increased, 6α-hydroxysugiol was obtained. Also an interesting formation of the cis aminol derivatives was synthesized from cis epoxide 12. | Versión del editor: | https://doi.org/10.1016/j.tetlet.2013.06.048 | URI: | http://hdl.handle.net/10261/178667 | DOI: | 10.1016/j.tetlet.2013.06.048 | Identificadores: | doi: 10.1016/j.tetlet.2013.06.048 issn: 0040-4039 |
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