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Absolute configuration of indoline alkaloids from Geissospermum reticulatum

AuthorsGordillo-Román, Bárbara; Reina, Matías ; Ruiz-Mesía, Lastenia; Ruiz-Mesía, Wilfredo; Joseph-Nathan, Pedro
Absolute configuration
Aspidospermatan-type alkaloids
Indoline alkaloids
Issue Date27-Mar-2013
CitationTetrahedron Letters 54(13): 1693-1696 (2013)
AbstractThe absolute configuration (AC) of (+)-2R,7R,15R,17S,19S-10-demethoxy-12-hydroxy-17,19-epoxygeissovelline (1), a main aspidospermatan-type indoline alkaloid from Geissospermum reticulatum, was established by vibrational circular dichroism (VCD), facilitating deduction of the AC of all structurally related alkaloids isolated from this plant.
Publisher version (URL)https://doi.org/10.1016/j.tetlet.2013.01.055
Identifiersdoi: 10.1016/j.tetlet.2013.01.055
issn: 0040-4039
Appears in Collections:(IPNA) Artículos
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