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dc.contributor.authorNeuman, Tomáš-
dc.contributor.authorEsteban, Ruben-
dc.contributor.authorCasanova, David-
dc.contributor.authorGarcía-Vidal, F. J.-
dc.contributor.authorAizpurua, Javier-
dc.date.accessioned2019-03-12T14:01:20Z-
dc.date.available2019-03-12T14:01:20Z-
dc.date.issued2018-
dc.identifierdoi: 10.1021/acs.nanolett.7b05297-
dc.identifiere-issn: 1530-6992-
dc.identifierissn: 1530-6984-
dc.identifier.citationNano Letters 18(4): 2358-2364 (2018)-
dc.identifier.urihttp://hdl.handle.net/10261/177791-
dc.description.abstractAs the size of a molecular emitter becomes comparable to the dimensions of a nearby optical resonator, the standard approach that considers the emitter to be a point-like dipole breaks down. By adoption of a quantum description of the electronic transitions of organic molecular emitters, coupled to a plasmonic electromagnetic field, we are able to accurately calculate the position-dependent coupling strength between a plasmon and an emitter. The spatial distribution of excitonic and photonic quantum states is found to be a key aspect in determining the dynamics of molecular emission in ultrasmall cavities both in the weak and strong coupling regimes. Moreover, we show that the extreme localization of plasmonic fields leads to the selection rule breaking of molecular excitations.-
dc.description.sponsorshipJ.A., R.E., and T.N. acknowledge the project FIS2016-80174-P from MINECO, project 70NANB15H32 from U.S. Department of Commerce, National Institute of Standards and Technology, and project PI2017-30 of the Department of Education of the Basque Government. F.J.G.-V. acknowledges funding by the European Research Council under Grant Agreement ERC-2011-AdG 290981 and by the Spanish MINECO under contract MAT2014-53432-C5-5-R. D.C. acknowledges project CTQ2016-80955 from MINECO.-
dc.publisherAmerican Chemical Society-
dc.relationMINECO/ICTI2013-2016/FIS2016-80174-P-
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/290981-
dc.relationMINECO/ICTI2013-2016/MAT2014-53432-C5-5-R-
dc.relationMINECO/ICTI2013-2016/CTQ2016-80955-P-
dc.rightsclosedAccess-
dc.subjectSingle-molecule spectroscopy-
dc.subjectPoint-dipole approximation-
dc.subjectNanoplasmonics-
dc.subjectQuantum nano-optics-
dc.subjectPlasmon−exciton coupling-
dc.subjectQuantum chemistry-
dc.titleCoupling of molecular emitters and plasmonic cavities beyond the point-dipole approximation-
dc.typeartículo-
dc.date.updated2019-03-12T14:01:21Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderDepartment of Commerce (US)-
dc.contributor.funderEusko Jaurlaritza-
dc.contributor.funderEuropean Research Council-
dc.contributor.funderEuropean Commission-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/100000190es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000781es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003086es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.pmid29522686-
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