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Building a 22-ring nanographene by combining in-solution and on-surface syntheses

AuthorsZuzak, Rafał; Castro-Esteban, Jesús; Brandimarte, Pedro; Engelund, Mads; Cobas, Agustín; Piątkowski, Piotr; Kolmer, Marek; Pérez, Dolores; Guitián, Enrique; Szymonski, Marek; Sánchez-Portal, Daniel CSIC ORCID ; Godlewski, Szymon; Peña, Diego
Issue Date2018
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 54(73): 10256-10259 (2018)
AbstractA nanographene formed by the fusion of 22 benzene rings has been prepared by combining an in-solution Pd-catalyzed cycloaddition reaction and on-surface Au-promoted cyclodehydrogenation. The structure and electronic properties of the resulting three-fold symmetric CH molecule have been characterized by scanning probe microscopy with atomic resolution and corroborated by theoretical modelling.
Identifiersdoi: 10.1039/C8CC05353G
e-issn: 1364-548X
issn: 1359-7345
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