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dc.contributor.authorLeón-Boigues, Laia-
dc.contributor.authorBilderling, Catalina von-
dc.contributor.authorPietrasanta, Lía I.-
dc.contributor.authorAzzaroni, O.-
dc.contributor.authorGiussi, Juan M.-
dc.contributor.authorMijangos, Carmen-
dc.date.accessioned2019-03-01T10:51:02Z-
dc.date.available2019-03-01T10:51:02Z-
dc.date.issued2019-02-09-
dc.identifier.citationPolymers 11(2): 290 (2019)-
dc.identifier.issn2073-4360-
dc.identifier.urihttp://hdl.handle.net/10261/177061-
dc.description.abstractThe tunable swelling and mechanical properties of nanostructures polymers are crucial parameters for the creation of adaptive devices to be used in diverse fields, such as drug delivery, nanomedicine, and tissue engineering. We present the use of anodic aluminum oxide templates as a nanoreactor to copolymerize butyl methacrylate and 2-hydroxyethyl acrylate under radical conditions. The copolymer obtained under confinement showed significant differences with respect to the same copolymer obtained in bulk conditions. Molecular weights, molecular weight dispersities, Young’s modulus, and wetting behaviors were significantly modified. The combination of selected monomers allowed us to obtain nanopillar structures with an interesting softening surface and extraordinary swelling capacity that could be of special interest to surface science and specifically, cell culture.-
dc.description.sponsorshipThis research was funded by Ministerio de Economía y Competitividad (MAT2017-83014-C2-2-P and MAT 2014-53437-C2-1P) from Spain and by Agencia Nacional de Promoción Científica y Tecnológica (PICT-2013-0905, PICT-2015-0346) and Universidad Nacional de La Plata (PPID-2018) from Argentina-
dc.description.sponsorshipWe acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI)-
dc.publisherMultidisciplinary Digital Publishing Institute-
dc.relationMINECO/ICTI2013-2016/MAT2017-83014-C2-2-P-
dc.relationMINECO/ICTI2013-2016/MAT2014-53437-C2-1P-
dc.relation.isversionofPublisher's version-
dc.rightsopenAccess-
dc.subjectAnodic aluminum oxide template-
dc.subjectFree radical copolymerization-
dc.subjectSwelling and mechanical properties-
dc.titleA Patterned Butyl Methacrylate-co-2-Hydroxyethyl Acrylate Copolymer with Softening Surface and Swelling Capacity-
dc.typeArtículo-
dc.identifier.doi10.3390/polym11020290-
dc.description.peerreviewedPeer reviewed-
dc.relation.publisherversionhttp://dx.doi.org/10.3390/polym11020290-
dc.date.updated2019-03-01T10:51:02Z-
dc.rights.licensehttp://creativecommons.org/licenses/by-nc-sa/4.0/-
dc.rights.licensehttp://creativecommons.org/licenses/by-nc-sa/4.0/-
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)-
dc.contributor.funderMinisterio de Economía y Competitividad (España)-
dc.contributor.funderAgencia Nacional de Promoción Científica y Tecnológica (Argentina)-
dc.contributor.funderUniversidad Nacional de Mar del Plata-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100007070es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003074es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
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