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Título: | Cycloosmathioborane compounds: Other manifestations of the Hückel aromaticity |
Autor: | Esteruelas, Miguel A. CSIC ORCID; Fernández, Israel; García-Yebra, Cristina CSIC ORCID; Martín, Jaime CSIC ORCID; Oñate, Enrique CSIC ORCID | Fecha de publicación: | 2019 | Editor: | American Chemical Society | Citación: | Inorganic Chemistry 58(4): 2265-2269 (2019) | Resumen: | The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH3NHR2 amine–borane, bear an Os–S–B three-membered ring, being a manifestation of the 4n + 2 Hückel aromaticity in which n = 0 and where the two π electrons of the ring are provided by the S atom. | Versión del editor: | https://doi.org/10.1021/acs.inorgchem.8b03366 | URI: | http://hdl.handle.net/10261/176297 | DOI: | 10.1021/acs.inorgchem.8b03366 | ISSN: | 0020-1669 | E-ISSN: | 1520-510X |
Aparece en las colecciones: | (ISQCH) Artículos |
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Revised-Jaime-InorgChem.pdf | 692,31 kB | Adobe PDF | Visualizar/Abrir |
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