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Title

Synthesis of medium-sized lactones: Iodosobenzene diacetate an efficient reagent for β-fragmentation of alkoxy-radicals

AuthorsFreire, Raimundo ; Marrero, José J.; Rodríguez Morales, María S. ; Suárez, Ernesto
Issue Date1986
PublisherElsevier
CitationTetrahedron Letters 27(3): 383-386 (1986)
AbstractPhotolysis of several steroidal lactols in the presence of iodosobenzene diocetate (IBDA) and iodine leads to alkoxy-radicals, which undergo β-fragmentation to produce medium-sized lactones in good yields.
Description4 pages, 2 schemes.-- Part of the thesis of M.R.M.-- The work described here was presented at the "XI Reunión Bienal de Química Orgánica", Sep 1985, Valladolid, Spain.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)84025-3
URIhttp://hdl.handle.net/10261/17593
DOI10.1016/S0040-4039(00)84025-3
ISSN0040-4039
Appears in Collections:(IPNA) Artículos
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