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Title

Intramolecular functionalization of amides leading to lactams

AuthorsHernández, Rosendo CSIC; Medina, María C.; Salazar, José A.; Suárez, Ernesto CSIC ORCID; Prangé, Thierry
Issue Date1987
PublisherElsevier
CitationTetrahedron Letters 28(22): 2533-2536 (1987)
AbstractFormation of lactams is observed by photolysis of amides in the presence of the iodosobenzene diacetate/I2 system and other oxidation agents through intramolecular functionalization of non-activated carbons involving a 1,6- or 1,5-hydrogen shift.
Photolysis of the steroidal amide (1) in the presence of several oxidation agents gave the δ-lactams (2) and (3).
Description4 pages, 1 figure, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)95460-1
URIhttp://hdl.handle.net/10261/17592
DOI10.1016/S0040-4039(00)95460-1
ISSN0040-4039
Appears in Collections:(IPNA) Artículos

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