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| Title: | Intramolecular functionalization of amides leading to lactams |
Authors: | Hernández, Rosendo CSIC; Medina, María C.; Salazar, José A.; Suárez, Ernesto CSIC ORCID; Prangé, Thierry | Issue Date: | 1987 | Publisher: | Elsevier | Citation: | Tetrahedron Letters 28(22): 2533-2536 (1987) | Abstract: | Formation of lactams is observed by photolysis of amides in the presence of the iodosobenzene diacetate/I2 system and other oxidation agents through intramolecular functionalization of non-activated carbons involving a 1,6- or 1,5-hydrogen shift. Photolysis of the steroidal amide (1) in the presence of several oxidation agents gave the δ-lactams (2) and (3). |
Description: | 4 pages, 1 figure, 1 table, 2 schemes. | Publisher version (URL): | http://dx.doi.org/10.1016/S0040-4039(00)95460-1 | URI: | http://hdl.handle.net/10261/17592 | DOI: | 10.1016/S0040-4039(00)95460-1 | ISSN: | 0040-4039 |
| Appears in Collections: | (IPNA) Artículos |
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