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Título: | Lignin monomers from the flavonoid and stilbene biosynthetic pathways |
Autor: | Río Andrade, José Carlos del CSIC ORCID ; Rencoret, Jorge CSIC ORCID; Gutiérrez Suárez, Ana CSIC ORCID ; Lan, Wu; Kim, Hoon; Ralph, John | Fecha de publicación: | jul-2018 | Editor: | Groupe Polyphénols | Citación: | XXIXth International Conference on Polyphenols and 9th Tannin Conference (2018) | Resumen: | Lignin is a phenylpropanoid polymer derived from the oxidative radical coupling of three p-hydroxycinnamyl alcohols (so-called “monolignols”) differing in their degree of methoxylation, p-coumaryl, coniferyl, and sinapyl alcohols. Several other phenolic compounds, all deriving from the shikimate-derived monolignol biosynthetic pathway, have been found to behave as lignin monomers in many plants, including the monolignol ester conjugates (with acetate, p-coumarate, ferulate, and p-hydroxybenzoate) or the incompletely methylated monomers caffeyl and 5-hydroxyconiferyl alcohols, among others. However, recent studies have revealed that some phenolic compounds derived from other biosynthetic pathways also act as true lignin monomers participating in coupling and cross-coupling reactions during lignification in several plants. This is the case for the flavone tricin recently established as a monomer in the lignins from grasses and other monocots (and the flavanone naringenin found in the lignin in an fnsII rice mutant) or the newly discovered hydroxystilbenes (resveratrol, isorhapontigenin and piceatannol) that are implicated as monomers in the lignin of palm fruit endocarps. The discovery in lignins of ‘non-conventional’ phenolic precursors arising from other biosynthetic pathways than the canonical monolignol biosynthetic pathway expands the traditional definition of lignin and reveals that any phenolic compound that is delivered to the cell wall may be oxidized and incorporated into the lignin polymer during lignification, subject exclusively to its chemical compatibility | Descripción: | Comunicación oral presentada en la XXIX Conferencia Internacional sobre Polifenoles y la 9ª Conferencia de Taninos, del 16 al 20 de julio de 2018 Madison, WI, USA | URI: | http://hdl.handle.net/10261/175187 |
Aparece en las colecciones: | (IRNAS) Comunicaciones congresos |
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