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http://hdl.handle.net/10261/173445
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Arévalo, Rebeca | - |
dc.contributor.author | Riera, Lucía | - |
dc.contributor.author | Pérez, Julio | - |
dc.date.accessioned | 2018-12-20T10:19:22Z | - |
dc.date.available | 2018-12-20T10:19:22Z | - |
dc.date.issued | 2017 | - |
dc.identifier | doi: 10.1021/acs.inorgchem.7b00078 | - |
dc.identifier | e-issn: 1520-510X | - |
dc.identifier | issn: 0020-1669 | - |
dc.identifier.citation | Inorganic Chemistry 56(8): 4249-4252 (2017) | - |
dc.identifier.uri | http://hdl.handle.net/10261/173445 | - |
dc.description.abstract | Intramolecular C-C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO) fragments. The nucleophilic CH group generated by the deprotonation attacks the 6 (bipy) or 2 (phen) positions of the diimines, dearomatizing the involved pyridine ring and generating new asymmetric, fac-capping tridentate ligands. | - |
dc.description.sponsorship | The authors thank MINECO and FEDER (Grant CTQ2015-70231-P) and Principado de Asturias (Grant FC-15-GRUPIN14-103) for funding and the Ministerio de Educación for an FPU predoctoral fellowship (to R.A.). | - |
dc.publisher | American Chemical Society | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-70231-P | - |
dc.rights | closedAccess | - |
dc.title | Interligand C-C coupling between α-methyl N-heterocycles and bipy or phen at rhenium tricarbonyl complexes | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1021/acs.inorgchem.7b00078 | - |
dc.date.updated | 2018-12-20T10:19:22Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | European Commission | - |
dc.contributor.funder | Principado de Asturias | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.contributor.funder | Ministerio de Educación (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/100011941 | es_ES |
dc.identifier.pmid | 28368589 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.openairetype | artículo | - |
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