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Title

Interligand C-C coupling between α-methyl N-heterocycles and bipy or phen at rhenium tricarbonyl complexes

AuthorsArévalo, Rebeca; Riera, Lucía ; Pérez, Julio
Issue Date2017
PublisherAmerican Chemical Society
CitationInorganic Chemistry 56(8): 4249-4252 (2017)
AbstractIntramolecular C-C coupling between N-bonded 1,2-dimethylimidazole, 2-methyloxazoline, or 2-methylpyridine and either 2,2′-bipyridine (bipy) or 1,10-phenanthroline (phen) ligands results from α-methyl group deprotonation in the coordination sphere of Re(CO) fragments. The nucleophilic CH group generated by the deprotonation attacks the 6 (bipy) or 2 (phen) positions of the diimines, dearomatizing the involved pyridine ring and generating new asymmetric, fac-capping tridentate ligands.
URIhttp://hdl.handle.net/10261/173445
Identifiersdoi: 10.1021/acs.inorgchem.7b00078
e-issn: 1520-510X
issn: 0020-1669
Appears in Collections:(CINN) Artículos
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