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Título: | Ab initio crystal structure determination, thermal behaviour, and magnetic characterization of a new nickel coordination polymer based on carboxyethylphosphonic acid and 4,4′-bipyridine |
Autor: | Fernández-Zapico, E. CSIC; Silva, Iván da CSIC ORCID; Mendoza-Meroño, Rafael CSIC ORCID; Montejo-Bernardo, J. M. CSIC; Martínez-Blanco, David; García-Granda, Santiago CSIC ORCID ; García, José R. CSIC ORCID | Palabras clave: | Magnetic characterization Hydrothermal synthesis Ab initio crystal structure determination Thermal characterization Nickel phosphonates |
Fecha de publicación: | 2016 | Editor: | Elsevier | Citación: | Inorganica Chimica Acta 448: 78-85 (2016) | Resumen: | Crystalline powder aggregates of a new nickel coordination polymer with 2-carboxyethylphosphonic acid (HPPAH) and 4,4′-bipyridine, Ni(HPPA)(4,4′-bipy)(HO), has been obtained by hydrothermal synthesis, and their crystal structure has been ab initio determined from synchrotron powder data. The compound shows a layer structure in bc plane, with Ni atoms in two different environments. The loss of the coordinated water by heating leads to the apparition of an anhydrous phase, which remains stable when cooling down to room temperature. Synthesized material presents a paramagnetic behaviour with weak antiferromagnetic interactions and zero-field splitting at low temperature (T < 50 K). | URI: | http://hdl.handle.net/10261/173156 | DOI: | 10.1016/j.ica.2016.04.038 | Identificadores: | doi: 10.1016/j.ica.2016.04.038 issn: 0020-1693 |
Aparece en las colecciones: | (CINN) Artículos (ICMM) Artículos |
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