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dc.contributor.authorMoral-Vico, Javieres_ES
dc.contributor.authorCasañ Pastor, Nieveses_ES
dc.contributor.authorCamón, Agustínes_ES
dc.contributor.authorPobes, Carloses_ES
dc.contributor.authorJáudenes, Rosa M.es_ES
dc.contributor.authorStrichovanec, Paveles_ES
dc.contributor.authorFàbrega, Lourdeses_ES
dc.date.accessioned2018-12-03T10:10:36Z-
dc.date.available2018-12-03T10:10:36Z-
dc.date.issued2019-01-01-
dc.identifier.citationJournal of Electroanalytical Chemistry 832: 40-47 (2019)es_ES
dc.identifier.issn1572-6657-
dc.identifier.urihttp://hdl.handle.net/10261/172885-
dc.description.abstractThe semimetal character of bismuth and its large photon absorbing power make of this element the most suitable absorber material for X-ray low temperature detectors. This application requires coatings of Bi with thicknesses and properties that only electrodeposition methods may achieve. Although there are studies on electrodeposition of bismuth for these detectors and other devices, the process is not straightforward and has not been sufficiently studied in terms of the desired final properties, neither the effect of different parameters is well known or easily reproduced. This work reports the influence of two different electrolytes, of the deposition method, and of heating and stirring on the structure, microstructure and transport properties of bismuth films. Typically, rhombohedral Bi is obtained upon electrodeposition with very good crystallinity, and some crystal preferential orientation, while significant empirical correlations are found among electrochemical parameters, microstructure, and resistivity. Such correlation allows the identification of the deposition parameters for coatings that yield the optimal functional properties.es_ES
dc.description.sponsorshipWork financed by the Spanish Ministerio de Economía y Competitividad-MINECO (projects ESP2014-53672-C3-2-P, ESP2016-76683-C3-2-R and ESP2014-59309-JIN), the European Space Agency-ESA (CTP Contract “Optimization of a European TES array”) and the European Commission (H2020 project AHEAD: “Integrated activities for the high energy astrophysics domain”). Personnel from ICMAB acknowledge financial support from MINECO, through the “Severo Ochoa” Programme for Centres of Excellence in R&D (SEV-2015-0496). RMJ wishes to thank MINECO for her FPI contract. We acknowledge also the help of Guillermo Antorrena (INA) on XPS data.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relationMINECO/ICTI2013-2016/ESP2014-53672-C3-2-Pes_ES
dc.relationMINECO/ICTI2013-2016/ESP2016-76683-C3-2-Res_ES
dc.relationMINECO/ICTI2013-2016/ESP2014-59309-JINes_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/654215es_ES
dc.relationMINECO/ICTI2013-2016/SEV-2015-0496es_ES
dc.relation.isversionofPostprintes_ES
dc.rightsembargoedAccesses_ES
dc.subjectBismuthes_ES
dc.subjectElectrodepositiones_ES
dc.subjectResistivityes_ES
dc.subjectLow temperature detectorses_ES
dc.titleMicrostructure and electrical transport in electrodeposited Bi filmses_ES
dc.typeartículoes_ES
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.jelechem.2018.10.041es_ES
dc.embargo.terms2021-01-01es_ES
dc.rights.licensehttp://creativecommons.org/licenses/by-nc-nd/4.0/-
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Space Agencyes_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000844es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
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