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Title

Alkoxy radical-induced transannular cyclizations of a substituted (E)-5-cyclodecenone derivative: Synthesis of bicyclo[5.3.0]decanes

AuthorsArencibia, Teresa; Prangé, Thierry; Salazar, José A.; Suárez, Ernesto CSIC ORCID
Issue Date28-Aug-1995
PublisherElsevier
CitationTetrahedron Letters 36(35): 6337-6340 (1995)
AbstractThe preparation of bicyclo[5.3.0]decanes from the steroidal 6α-substituted cyclodecenone 2 is described. The radical transannular cyclizations of the studied cyclodecenone are intramolecularly induced by a primary alkoxy radical, generated by photolysis using the (diacetoxyiodo)benzene/I2 or HgO/I2 systems.
Description4 pages, 2 figures, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/0040-4039(95)01225-7
URIhttp://hdl.handle.net/10261/17260
DOI10.1016/0040-4039(95)01225-7
ISSN0040-4039
Appears in Collections:(IPNA) Artículos

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