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1,3-Transposition of primary allylic alcohols: Synthesis of optically active secondary and tertiary allylic alcohols

AuthorsDorta, Rosa L. ; Rodríguez Morales, María S. ; Salazar, José A.; Suárez, Ernesto
Issue Date30-Jun-1997
CitationTetrahedron Letters 38(26): 4675-4678 (1997)
AbstractThe reduction of optically active 2,3-epoxy alcohols, suitably prepared by the Sharpless asymmetric epoxidation of primary allylic alcohols, with the system triphenylphosphine/iodine/imidazole/2,6-lutidine/water, leads in a single step to optically active secondary and tertiary allylic alcohols.
Description4 pages, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(97)00964-7
Appears in Collections:(IPNA) Artículos
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