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Synthesis of dispiroacetals from carbohydrates by intramolecular hydrogen abstractions

AuthorsDorta, Rosa L. ; Martín, Ángeles ; Salazar, José A.; Suárez, Ernesto ; Prangé, Thierry
Issue Date12-Aug-1996
CitationTetrahedron Letters 37(33): 6021-6024 (1996)
AbstractThe synthesis of 1,6,8-trioxadispiro[]pentadecanes 15 and 16 from D-galactopyranose is described. The key steps are two intramolecular hydrogen abstraction reactions promoted by alkoxy radicals.
Description4 pages, 1 figure, 4 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/0040-4039(96)01265-8
Appears in Collections:(IPNA) Artículos
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