Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/17240
Share/Export:
logo share SHARE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

Radical β-fragmentation of bicyclo[3.3.0]-carbinolamides: Synthesis of five- and eight-membered cyclic imides

AuthorsHernández, Rosendo CSIC; Melián, Daniel; Prangé, Thierry; Suárez, Ernesto CSIC ORCID
Issue Date1995
PublisherElsevier
CitationHeterocycles 41(3): 439-454 (1995)
AbstractThe influence of 4-alkyl or 4-aryl substituents in the regioselectivity of the β-fragmentation of carbinolamidyl radicals generated from the corresponding carbinolamides (7-13) by irradiation with visible light in the presence of (diacetoxyiodo)benzene and iodine is described. In the case of the less hindered carbinolamides 1-hydroxyazabicyclo[3.3.0]octan-3-one (7) and 4-(2'-phenylethyl)-1-hydroxyazabicyclo[3.3.0]octan-3-one (8) important amounts of 8-membered cyclic imides were obtained together with the expected 5-membered imides (succinimides).
Description16 pages, 1 figure, 1 table, 2 schemes.
Publisher version (URL)http://linkinghub.elsevier.com/retrieve/pii/0385541495940565
URIhttp://hdl.handle.net/10261/17240
ISSN0385-5414
Appears in Collections:(IPNA) Artículos

Show full item record
Review this work

Page view(s)

301
checked on Jul 2, 2022

Google ScholarTM

Check


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.