English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/17234
Share/Impact:
Statistics
logo share SHARE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
DC FieldValueLanguage
dc.contributor.authorFrancisco, Cosme G.en_US
dc.contributor.authorHerrera, Antonio J.en_US
dc.contributor.authorSuárez, Ernestoen_US
dc.date.accessioned2009-09-29T07:47:59Z-
dc.date.available2009-09-29T07:47:59Z-
dc.date.issued2000-10-06en_US
dc.identifier.citationTetrahedron Asymmetry 11(19): 3879-3882 (2000)en_US
dc.identifier.issn0957-4166-
dc.identifier.urihttp://hdl.handle.net/10261/17234-
dc.description4 pages, 1 table, 1 scheme.-
dc.description.abstractHomochiral 7-oxa-2-azabicyclo[2.2.1]heptane and 8-oxa-6-azabicyclo[3.2.1]octane ring systems can be synthesized by reaction of specifically protected phosphoramidate derivatives of carbohydrates with (diacetoxyiodo)benzene or iodosylbenzene and iodine. The reaction mechanism goes through homolytic fragmentation of a hypothetical iodoamide intermediate. The N-radicals so generated participate in an intramolecular hydrogen abstraction reaction (IHA) to give the aforementioned bicycles.-
dc.description.sponsorshipThis work was supported by Investigation Programme PB96-1461 of the Direction General de Investigación Científica y Técnica. A.J.H. thanks the Ministerio de Educación y Ciencia, Spain, for a fellowship.-
dc.format.extent2373 bytes-
dc.format.extent404728 bytes-
dc.format.mimetypetext/plain-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherElsevier-
dc.rightsclosedAccessen_US
dc.titleIntramolecular hydrogen abstraction promoted by N-radicals: synthesis of chiral 7-oxa-2-azabicyclo[2.2.1]heptane and 8-oxa-6-azabicyclo[3.2.1]octane ring systemsen_US
dc.typeartículoen_US
dc.identifier.doi10.1016/S0957-4166(00)00364-5-
dc.relation.publisherversionhttp://dx.doi.org/10.1016/S0957-4166(00)00364-5-
dc.contributor.funderMinisterio de Educación y Ciencia (España)-
dc.contributor.funderDirección General de Investigación Científica y Técnica, DGICT (España)-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100008737es_ES
Appears in Collections:(IPNA) Artículos
Files in This Item:
There are no files associated with this item.
Show simple item record
 


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.