English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/171092
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

The structure of fosfomycin salts in solution and in the solid state by nuclear magnetic resonance spectroscopy and DFT calculations

AuthorsPérez Torralba, Marta; Sanz, Dionisia; Claramunt, Rosa M.; Alkorta, Ibon ; Dardonville, Christophe ; Elguero, José
KeywordsFosfomycin
NMR
SSNMR
DFT
GIAO
Phosphomycin
Issue Date2018
PublisherElsevier
CitationTetrahedron 74: 3937-3942 (2018)
AbstractTwo samples of fosfomycin salts, the calcium and the disodium ones, were used to record their NMR spectra both in solution and in the solid state. The existence of fosfomycin in a neutral and two ionized structures (mono and dianion) was considered to interpret the spectra that were solved using the GIAO calculated chemical shifts of the minimum energy conformations. Although the starting materials were dianions, the spectra in solution show the presence of monoanions.
Publisher version (URL)MINECO/ICTI2013-2016/CTQ2014-56833-R
http://dx.doi.org/10.1016/j.tet.2018.02.041
URIhttp://hdl.handle.net/10261/171092
Identifiersdoi: 10.1016/j.tet.2018.02.041
issn: 1464-5416
Appears in Collections:(IQM) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.